Skip to Main Content
U.S. Forest Service
Caring for the land and serving people

United States Department of Agriculture

Home > Search > Publication Information

  1. Share via EmailShare on FacebookShare on LinkedInShare on Twitter
    Dislike this pubLike this pub

    Description

    The goal of this work is to produce nanocomposite film with low oxygen permeability by casting an aqueous solution containing xylan, sorbitol and nanocrystalline cellulose. The morphology of the resulting nanocomposite films was examined by scanning electron microscopy and atomic force microscopy which showed that control films containing xylan and sorbitol had a more open structure as compared to xylan-sorbitol films containing sulfonated nanocrystalline cellulose. The average pore diameter, bulk density, porosity and tortuosity factor measurements of control xylan films and nanocomposite xylan films were examined by mercury intrusion porosimetry techniques. Xylan films reinforced with nanocrystalline cellulose were denser and exhibited higher tortuosity factor than the control xylan films. Control xylan films had average pore diameter, bulk density, porosity and tortuosity factor of 0.1730 μm, 0.6165 g/ml , 53.0161% and 1.258, respectively as compared to xylan films reinforced with 50% nanocrystalline cellulose with average pore diameter of 0.0581 μm, bulk density of 1.1513 g/ml, porosity of 22.8906% and tortuosity factor of 2.005. Oxygen transmission rate tests demonstrated that films prepared with xylan, sorbitol and 5%, 10%, 25% and 50% sulfonated nanocrystalline cellulose exhibited a significantly reduced oxygen permeability of 1.1387, 1.0933, 0.8986 and 0.1799 cm3⋅μm/m2⋅d⋅kPa respectively with respect to films prepared solely from xylan and sorbitol with a oxygen permeability of 189.1665 cm3⋅μm/m2⋅d⋅kPa. These properties suggested these nanocomposite films have promising barrier properties.

    Publication Notes

    • You may send email to pubrequest@fs.fed.us to request a hard copy of this publication.
    • (Please specify exactly which publication you are requesting and your mailing address.)
    • We recommend that you also print this page and attach it to the printout of the article, to retain the full citation information.
    • This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.

    Citation

    Saxena, Amit; Elder, Thomas J.; Kenvin, Jeffrey; Ragauskas, Arthur J. 2010. High oxygen nanocomposite barrier films based on xylan and nanocrystalline cellulose. Nano-Micro Letters 2(4):235-241.

    Cited

    Google Scholar

    Keywords

    Nanocomposites, Xylan, Nanocrystalline Cellulose, Oxygen Barrier

    Related Search


    XML: View XML
Show More
Show Fewer
Jump to Top of Page