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Thermal Expansion of Self-Organized and Shear-Oriented Cellulose Nanocrystal Films


Jairo A. Diaz
Xiawa Wu
Ashlie Martini
Jeffrey P. Youngblood



Publication type:

Scientific Journal (JRNL)

Primary Station(s):

Forest Products Laboratory


Biomacromolecules 2013, Volume 14, 2013; pp. 2900-2908.


The coefficient of thermal expansion (CTE) of cellulose nanocrystal (CNC) films was characterized using novel experimental techniques complemented by molecular simulations. The characteristic birefringence exhibited by CNC films was utilized to calculate the in-plane CTE of selforganized and shear-oriented self-standing CNC films from room temperature to 100 °C using polarized light image correlation. CNC alignment was estimated via Hermans order parameter (S) from 2D X-ray diffraction measurements. We found that films with no preferential CNC orientation through the thickness (S: ~­0.0) exhibited an isotropic CTE (~­25 ppm/K). In contrast, films with aligned CNC orientations (S: ~0.4 to 0.8) had an anisotropic CTE response: For the highest CNC alignment (S: 0.8), the CTE parallel to CNC alignment was ~­9 ppm/K, while that perpendicular to CNC alignment was ~158 ppm/K. CNC film thermal expansion was proposed to be due primarily to single crystal expansion and CNC-CNC interfacial motion. The relative contributions of inter- and intracrystal responses to heating were explored using molecular dynamics simulations.


Diaz, Jairo A.; Wu, Xiawa; Martini, Ashlie; Youngblood, Jeffrey P.; Moon, Robert J. 2013. Thermal expansion of self-organized and shear-oriented cellulose nanocrystal films. Biomacromolecules. 14: 2900-2908.


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