Highly thermal-stable and functional cellulose nanocrystals and nanofibrils produced using fully recyclable organic acidsAuthor(s): Liheng Chen; Junyong Zhu; Carlos Baez; Peter Kitin; Thomas Elder
Source: Green Chemistry
Publication Series: Scientific Journal (JRNL)
Station: Southern Research Station
Download Publication (5.0 MB)
DescriptionHere we report the production of highly thermal stable and functional cellulose nanocrystals (CNC) and nanofibrils (CNF) by hydrolysis using concentrated organic acids. Due to their low water solubility, these solid organic acids can be easily recovered after hydrolysis reactions through crystallization at a lower or ambient temperature. When dicarboxylic acids were used, the resultant CNC surface contained carboxylic acid groups which facilitate functionalization and dispersion in aqueous processing. The carboxylic acid group content was 0.1–0.4 mmol g−1 for CNC produced from a bleached eucalyptus kraft pulp (BEP) using oxalic acid at concentrations of 50–70 wt%. The onset thermal degradation temperature for the CNC was increased to 322 °C from 274 °C for the feed BEP fibers, compared with 218 °C for CNC produced from the same feed fibers using conventional concentrated sulfuric acid hydrolysis. The low strength (high pKa) of organic acids also resulted in CNC with longer lengths of approximately 275–380 nm and higher crystallinity than those produced using mineral acids. Fibrous cellulosic solid residue (FCSR) collected from acid hydrolysis was an excellent feedstock for producing CNF through subsequent mechanical fibrillation with low energy input. The ability to recover organic acids using a conventional and commercially proven crystallization method makes these organic acids uniquely suitable for sustainable and green production of cellulose nanomaterials. The resultant CNC and CNF with high thermal stability and a large aspect ratio are excellent for bio-composite applications.
- You may send email to email@example.com to request a hard copy of this publication.
- (Please specify exactly which publication you are requesting and your mailing address.)
- We recommend that you also print this page and attach it to the printout of the article, to retain the full citation information.
- This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.
CitationChen, Liheng; Zhu, J. Y.; Baez, Carlos; Kitin, Peter; Elder, Thomas. 2016. Highly thermal-stable and functional cellulose nanocrystals and nanofibrils produced using fully recyclable organic acids. The Royal Society of Chemistry, Green Chemistry. 18(13): 3835-3843. DOI: 10.1039/c6gc00687f
- Green and low-cost production of thermally stable and carboxylated cellulose Nanocrystals and nanofibrils using highly recyclable dicarboxylic acids
- Using a fully recyclable dicarboxylic acid for producing dispersible and thermally stable cellulose nanomaterials from different cellulosic sources
- Strong and Optically Transparent Films Prepared Using Cellulosic Solid Residue Recovered from Cellulose Nanocrystals Production Waste Stream
XML: View XML