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    Description

    Bagasse flour (BF) was liquefied using bi-component polyhydric alcohol (PA) as a solvent
    and phosphoric acid as a catalyst in a microwave reactor. The effect of BF to solvent ratio and
    reaction temperatures on the liquefaction extent and characteristics of liquefied products were
    evaluated. The results revealed that almost 75% of the raw bagasse was converted into liquid
    products within 9 min at 150 C with a BF to solvent ratio of 1/4. The hydroxyl and acid values of the
    liquefied bagasse (LB) varied with the liquefied conditions. High reaction temperature combining
    with low BF to solvent ratio resulted in a low hydroxyl number for the LB. The molecular weight
    and polydispersity of the LB from reactions of 150 C was lower compared to that from 125 C. Rigid
    polyurethane (PU) foams were prepared from LB and methylene diphenyl diisocyanate (MDI), and
    the structural, mechanical and thermal properties of the PU foam were evaluated. The PU foams
    prepared using the LB from high reaction temperature showed better physical and mechanical
    performance in comparison to those from low reaction temperature. The amount of PA in the
    LB has the ability of increasing thermal stability of LB-PU foams. The results in this study may
    provide fundamental information on integrated utilizations of sugarcane bagasse via microwave
    liquefaction process.

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    Citation

    Xie, Jiulong; Zhai, Xianglin; Hse, Chung; Shupe, Todd; Pan, Hui. 2015. Polyols from microwave liquefied bagasse and its application to rigid polyurethane foam. Materials, Vol. 8(12): 14 pages.: 8496-8509.  10.3390/ma8125472

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    Keywords

    liquefaction, bagasse, microwave, polyhydric alcohol, polyurethane foams

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https://www.fs.usda.gov/treesearch/pubs/52716