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Low temperature synthesis of graphene-encapsulated copper nanoparticles from kraft ligninAuthor(s): Weiqi Leng; H. Michael Barnes; Qiangu Yan; Zhiyong Cai; Jilei Zhang
Source: Materials Letters. 185: 131-134.
Publication Series: Scientific Journal (JRNL)
Station: Forest Products Laboratory
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DescriptionThe formation of graphene-encapsulated copper nanoparticles was investigated through carbonizing a mixture of kraft lignin and copper sulfate pentahydrate at the temperature up to 500 °C. The abrupt conversion of copper ions into its atoms occurred at 300 °C. The formation of graphene layers surrounding copper nanoparticles started as early as the heating temperature reached 400 °C. Most copper nanoparticles were covered with less than five graphene layers when the temperature reached 500 °C. The average diameter of graphene-encapsulated copper nanoparticles was 12.75 and 11.62 nm for temperature at 400 and 500 °C, respectively. The heating temperature had no significant effect on the size of graphene-encapsulated copper nanoparticles in the evaluated temperature range. It is believed that the formation of graphene-layered shell surrounding copper nanoparticles is based on the mechanism of self-limiting theory with solid carbon as the carbon source.
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CitationLeng, Weiqi; Barnes, H. Michael; Yan, Qiangu; Cai, Zhiyong; Zhang, Jilei. 2016. Low temperature synthesis of graphene-encapsulated copper nanoparticles from kraft lignin. Materials Letters. 185: 131-134.
KeywordsForming process, mechanism, graphene encapsulated copper, nanoparticles
- Temperature and copper concentration effects on the formation of graphene-encapsulated copper nanoparticles from kraft lignin
- Temperature effects on formation of carbon-based nanomaterials from kraft lignin
- Catalytic conversion of Kraft lignin to bio-multilayer graphene materials under different atmospheres
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