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    Author(s): Eric S. Edgerton; Yu-Mei Hsu; Emily M. White; Mark E. Fenn; Matthew S. Landis
    Date: 2020
    Source: Science of The Total Environment. 706: 134864
    Publication Series: Scientific Journal (JRNL)
    Station: Pacific Southwest Research Station
    PDF: Download Publication  (5.0 MB)

    Description

    Trace gas, particulate matter and deposition data collected in the Athabasca Oil Sands Region (AOSR) from 2000 to 2017 were evaluated as part of a broad scientific programmatic review. Results showed significant spatial patterns and temporal trends across the region. Concentrations of reactive gases were highest near the center of surface oil sands production operations and decreased towards the edges of the monitoring domain by factors of 8, 20, 4 and 3 for SO2, NO2, HNO3 and NH3, respectively. 18 of 30 sites showed statistically significant (p < 0.05) negative trends in SO2 concentrations suggesting an ~40% decrease since 2000. In contrast, only 2 of 30 sites showed statistically significant temporal trends (1 positive, 1 negative) for NO2. NH3 data showed (i) intermittent wildfire impacts, and (ii) high seasonality, with low concentrations during winter and significantly higher values during the summer. PM10 measurements were more limited, but also showed significant spatio-temporal variability. Comparison of PM10 and PM2.5 data showed that >80% of SO42− was in the PM2.5 fraction, while > 60% of Ca2+, Mg2+, Na+ and Cl were in the PM10-2.5 fraction. Ion balances of both PM10 and PM2.5 contained cation excesses at near-field oil sand sites, but PM2.5 samples at forest health sites >20 km from surface production locations contained anion excesses. Monthly average concentrations of PM10 ions showed peak Ca2+ during March-April to November, but peak SO42−, NH4+ and NO3 from November-March. Deposition estimates showed rapid declines as a function of distance to oil sand operations. Estimated total N and total S deposition to forest health monitoring sites ranged from 2.0 to 5.7 kg ha−1 a−1 and 2.1–14.0 kg ha−1 a−1, respectively. Potential acid input (PAI) ranged from −0.46 to 0.79 keq ha−1 a−1 and was mostly 0.1–0.2 keq ha−1 a−1 throughout the domain, except for two clusters of sites near oil sand operations.

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    Citation

    Edgerton, Eric S.; Hsu, Yu-Mei; White, Emily M.; Fenn, Mark E.; Landis, Matthew S. 2020. Ambient concentrations and total deposition of inorganic sulfur, inorganic nitrogen and base cations in the Athabasca Oil Sands Region. Science of The Total Environment. 706: 134864. https://doi.org/10.1016/j.scitotenv.2019.134864.

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    Keywords

    Sulfur, Nitrogen, Base cations, Atmospheric deposition, Nitric acid, Ammonia, Boreal forest, Oil sands

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