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Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomenaAuthor(s): Yurii V. Geletii; Rajai H. Atalla; Alan J. Bailey; Laurent Delannoy; Craig L. Hill; Ira A. Weinstock
Source: Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165
Publication Series: Miscellaneous Publication
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DescriptionEarly transition-metal oxygen-anion clusters (polyoxometalates, POMs) are a large and rapidly growing class of versatile and tunable oxidation catalysts. All key molecular properties of these clusters (composition, size, shape, charge density, reduction potential, solubility, etc.) can be systematically altered, and the clusters themselves can serve as tunable ligands for controlling the reactivity of a wide variety of transition-metal cations.
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CitationGeletii, Yurii V.; Atalla, Rajai H.; Bailey, Alan J.; Delannoy, Laurent; Hill, Craig L.; Weinstock, Ira A. 2002. Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomena. Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165
KeywordsPolyoxometalates, oxidation catalysis, electron-transfer phenomena
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