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    Author(s): Yurii V. Geletii; Rajai H. Atalla; Alan J. Bailey; Laurent Delannoy; Craig L. Hill; Ira A. Weinstock
    Date: 2002
    Source: Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165
    Publication Series: Miscellaneous Publication
    PDF: View PDF  (17 KB)

    Description

    Early transition-metal oxygen-anion clusters (polyoxometalates, POMs) are a large and rapidly growing class of versatile and tunable oxidation catalysts. All key molecular properties of these clusters (composition, size, shape, charge density, reduction potential, solubility, etc.) can be systematically altered, and the clusters themselves can serve as tunable ligands for controlling the reactivity of a wide variety of transition-metal cations.

    Publication Notes

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    • This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.

    Citation

    Geletii, Yurii V.; Atalla, Rajai H.; Bailey, Alan J.; Delannoy, Laurent; Hill, Craig L.; Weinstock, Ira A. 2002. Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomena. Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165

    Keywords

    Polyoxometalates, oxidation catalysis, electron-transfer phenomena

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