Skip to Main Content
Development and application of colorimetric microassay for determining boron-containing compoundsAuthor(s): S. Nami Kartal; Frederick Green
Source: Forest products journal. Vol. 52, no. 6 (June 2002): Pages 75-79
Publication Series: Miscellaneous Publication
PDF: View PDF (198 KB)
DescriptionThis paper describes the development of a microsssay for boron and the application of this microassay for evaluating leachability of boron by post-treatment of southern pine with the calcium precipitating agent NHA (N'N-napthaloylhydroxylamine). The microsssay method for quantitative estimation of boron content in treated wood and leachates is a microadaptation of the colorimetric azomethine-H method. The primary advantages of this microassay method are that it uses fewer reagents, uses smaller sample volumes, and conserves time for analysis when a large number of tests are required. Wood blocks were treated with boric acid, disodium octaborate tetrahydrate (DOT), and NHA solutions at several concentrations. Boron leaching performance was evaluated on the blocks using AWPA E11-97 standard method. Blocks treated sequentially with DOT and then with 0.5 or 1.0 percent NHA solutions showed -30% less boron leaching, whereas similar treatment with boric acid and 0.1% NHA solutions did not enhance boron retention compared with the blocks treated with only boric acid. We conclude that precipitation of NHA at higher concentrations decreases or limits boron leaching.
- We recommend that you also print this page and attach it to the printout of the article, to retain the full citation information.
- This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.
CitationKartal, S. Nami; Green, Frederick. 2002. Development and application of colorimetric microassay for determining boron-containing compounds. Forest products journal. Vol. 52, no. 6 (June 2002): Pages 75-79
KeywordsCalorimetric microassays, boron compounds, microassays
- Performance Characteristics of Borate Fatty Acid Formulations as Mold Inhibitors
- Effects of inorganic ions on leachability of wood preserving N'N-hydroxynapthalimide (NHA).
- Leachability of boron from wood treated with natural and semi-synthetic polymers and calcium precipitating agent
XML: View XML