United States Department of Agriculture
Recent measurements indicate significantly enhanced biogenic soil emissions of both nitric oxide (NO) and nitrous oxide (N2O) following surface burning. These enhanced fluxes persisted for at least 6 months following the burn. Simultaneous measurements indicate enhanced levels of...
Biochars produced from thermochemical conversions of biomass were evaluated by temperature programmed oxidation (TPO). This technique, used to characterize carbon deposits on petroleum cracking catalysts, provides information on the oxidative stability of carbonaceous solids, where higher temperature reactivity indicates greater structural order, an important property...
Wildfires are a significant fraction of global biomass burning and a major source of trace gas and particle emissions in the atmosphere. Understanding the air quality and climate implications of wildfires is difficult since the emissions undergo complex transformations due to aging processes during transport away from the source. As part of the third Fire Lab at...
A mathematical model is developed describing the natural smoldering of logs. It is considered the steady one dimensional propagation of infinitesimally thin fronts of drying, pyrolysis, and char oxidation in a horizontal semi-infinite log. Expressions for the burn rates, distribution profiles of temperature, and positions of the drying, pyrolysis, and smoldering fronts...
While the vast majority of carbon emitted by wildland fires is released as CO2, CO, and CH4, wildland fire smoke is nonetheless a rich and complex mixture of gases and aerosols. Primary emissions include significant amounts of CH4 and aerosol (organic aerosol and black carbon), which are short-lived climate forcers. In addition to CO2 and short-lived climate forcers,...
Longleaf pine (Pinus palustris Miller) forests in the southern United States are being restored and actively managed for a variety of goals including: forest products, biodiversity, C sequestration and forest resilience in the face of repeated isturbances from hurricanes and climate change. Managed southern pine forests can be sinks for atmospheric...
Emissions of trace gases and particulate matter from burning of biomass are generally factored into global climate models. Models for improving the estimates of the global annual release of emissions from biomass fires are presented. Estimates of total biomass consumed on a global basis range from 2 to 10 Pg (1 petagram = 1015 g) per year. New...
The role of water vapor, originated from the moisture content in vegetation, on the combustion process was investigated via simulating an opposed diffusion flame and a laminar premixed flame with pyrolysis gases as the fuel and air as the oxidizer. The fuel was mixed with water vapor, and the simulation was repeated for various water mole fractions. In both of the...
Frameworks for limiting ecosystem exposure to excess nutrients and acidity require accurate and complete deposition budgets of reactive nitrogen (Nr). While much progress has been made in developing total Nr deposition budgets for the U.S., current budgets remain limited by key data and knowledge gaps. Analysis of National Atmospheric Deposition Program Total...
Wildland fuels have been accumulating in the United States during at least the past half-century due to wildland fire management practices and policies. The additional fuels contribute to intense fire behavior, increase the costs of wildland fire control, and contribute to the degradation of local and regional air quality. The management of prescribed and wildland fire...
Detailed airborne measure ments of smoke plumes from seven prescribed burns of forest biomass residues leftover from timber harvests in Washington and Oregon are described. Measurements of particle size distributions in the plumes at 3.3 km downwind of the burns showed a prominent peak in the mass concentration for particles 0.25-0.30 µm in diameter. The total mass of...
Gas samples were collected in smoke plumes over the San Dimas Experimental Forest during a 400-acre prescribed chaparral fire on December 12, 1986. A helicopter was used to collect gas samples over areas of vigorous flaming combustion and over areas of mixed stages (vigorous/transitional/smoldering) of combustion. Sampling was conducted at altitudes as low as 35 m and...
Concurrent changes in climate, atmospheric nitrogen (N) deposition, and increasing levels of atmospheric carbon dioxide (CO2) affect ecosystems in complex ways. The DayCent-Chem model was used to investigate the combined effects of these human-caused drivers of change over the period 1980–2075 at seven forested montane and two alpine watersheds...
Pyrolysis of intact wildland fuels in the southern United States is being measured at bench, wind tunnel, and field scales as part of a larger research project to measure and model pyrolysis of wildland fuels to improve models used to predict prescribed fire behavior. Traditional pyrolysis experiments typically use dried, ground samples in either an inert or oxidizing...
Biomass burning (BB) is a major global source of trace gases and particles. Accurately representing the production and evolution of these emissions is an important goal for atmospheric chemical transport models. We measured a suite of gases and aerosols emitted from an 81 hectare prescribed fire in chaparral fuels on the central coast of California, US on 17 November...